pH & pOH
pH SCALE
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
← acidic [H⁺]>10⁻⁷
neutral=7
basic [OH⁻]>10⁻⁷ →
| Substance | ≈ pH |
| Gastric acid | 1 |
| Lemon juice | 2 |
| Coffee | 5 |
| Pure water | 7 |
| Blood | 7.4 |
| Baking soda | 8.3 |
| Bleach | 12 |
STRONG ACIDS & BASES (fully dissociate)
Strong acids (memorise):
HCl, HNO₃, H₂SO₄, HBr, HI, HClO₄
[H⁺] strong
C × n_H (n_H = H⁺/molecule)
mono (HCl)
n_H = 1 → [H⁺] = C
diprotic (H₂SO₄)
n_H = 2 → [H⁺] = 2C
triprotic (H₃PO₄)
n_H = 3 → [H⁺] = 3C
Strong bases:
NaOH, KOH, LiOH, Ba(OH)₂, Ca(OH)₂
[OH⁻] = C × n_OH
WEAK ACIDS/BASES (partial dissociation)
- CH₃COOH, H₂CO₃, HF, H₂S, NH₃
- Use Ka or Kb + ICE table for [H⁺]
- Ka = [H⁺][A⁻] / [HA]
- Larger Ka = stronger weak acid
ICE TABLE
| HA | H⁺ | A⁻ |
| Initial | C | 0 | 0 |
| Change | −x | +x | +x |
| Equil. | C−x | x | x |
Ka
x² / (C−x) ≈ x²/C if x<5%
NEUTRALIZATION & TITRATION
Neutralization: acid + base → salt + water
Net ionic: H⁺(aq) + OH⁻(aq) → H₂O(l)
TITRATION (1:1 monoprotic)
CₐVₐ = CᵦVᵦ
mol acid = mol base at equiv.
nₐ, nᵦ = moles of H⁺/OH⁻ per formula unit
AT EQUIVALENCE POINT
| Combination | pH |
| Strong acid + strong base | = 7 |
| Strong acid + weak base | < 7 |
| Weak acid + strong base | > 7 |
COMMON INDICATORS
| Indicator | pH range | Colour change |
| Phenolphthalein | 8.2–10 | colourless→pink |
| Methyl orange | 3.1–4.4 | red→yellow |
| Litmus | 5–8 | red→blue |
| Bromothymol blue | 6–7.6 | yellow→blue |
COMMON ACIDS & THEIR H⁺
COMMON MISTAKES
- Weak acid ≠ dilute acid — strength = dissociation, not conc.
- H₂SO₄ diprotic: 0.1 M → [H⁺] = 0.2 M (×2!)
- Increasing pH means DECREASING [H⁺]
- pOH = 14 − pH (never 14 + pH)
- At equivalence: mol H⁺ = mol OH⁻ — check stoichiometry for diprotic
- Weak acid ICE: x ≈ √(Ka×C) only valid if x/C < 5%
WORKED EXAMPLES
0.050 M HCl:
[H⁺]=0.050 M → pH=−log(0.050)=1.30
0.010 M NaOH:
[OH⁻]=0.010 → pOH=2 → pH=12
CH₃COOH 0.10 M, Ka=1.8×10⁻⁵:
x=√(1.8×10⁻⁵×0.10)=1.34×10⁻³ M
pH=−log(1.34×10⁻³)=2.87
Titration: 25.0 mL HCl + 31.5 mL 0.100 M NaOH:
Cₐ=0.100×31.5/25.0=0.126 M